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• W2079401968 abstract "The photopolymerization of a number of neat acrylate monomers with acrylate functionality from 1−6 was studied with photoDSC (DSC = differential scanning calorimetry) and with a cure monitor using a fluorescent probe. PhotoDSC results show that conversion of monomers ranges from 40 to 100%, depending upon the functionality and structure of a monomer. Kinetics of a heat flow was well described as an autoaccelearted reaction for all monomers. Kinetics of the hardening of a sample under light at an ambient temperature was nicely fit into the two-exponential law; rate constants k1 and k2 in this empirical analysis were in the range of 0.5−35 min-1. The effect of an inhibitor and of air oxygen on kinetics of photopolymerization was also studied. The dependence of the rate of polymerization and conversion upon the functionality of a monomer is discussed." @default.
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• W2079401968 date "1999-07-30" @default.
• W2079401968 modified "2023-10-06" @default.
• W2079401968 title "Kinetics of Photopolymerization of Acrylates with Functionality of 1−6" @default.
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• W2079401968 doi "https://doi.org/10.1021/ie990306i" @default.
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