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- W2079402936 abstract "Potential-sweep voltammetric and potential-step chronoamperometric experiments were made at −50 °C with solvated electrons in methylamine containing LiCl, KI, or CsI. The dissociation rate constants of the ion pairs, (M + •e s − ), M being alkali metal and e s − free solvated electron, were greater than 10 3 s −1 . The pseudo-first-order rate constant of the dissociation of K − into the one-electron species, e s − and (K + •e s − ) in rapid equilibrium, was determined as 40 s −1 by chronoamperometry with 0.5 M KI solutions. The formation constants of K − from the one-electron species determined by chronoamperometry and voltammetry were 4.5 × 10 4 M −1 and 5.6 × 10 4 M −1 , respectively. An addition of a small amount of ammonia to methylamine caused a decrease in the formation constant of K − and an increase in its dissociation rate constant. The appendix deals with a theoretical treatment of chronoamperograms for an electrode process preceded by the dissociation of a dimer. The boundary value problem was solved by the explicit finite difference method and the analytical method which was based on the concept of reaction layer." @default.
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- W2079402936 date "1982-02-15" @default.
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- W2079402936 title "Dissociation kinetics of the solvated electron species in methylamine and methylamine–ammonia mixtures" @default.
- W2079402936 doi "https://doi.org/10.1139/v82-067" @default.
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