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- W2079403548 abstract "Sodalite absorption bands in the 50–350 cm−1 region were studied using Fourier transform spectroscopy. Vibrational modes were identified using chemical substitution, H2 and vacuum-annealing, and coloration studies. A bromosodalite band at 294 cm−1 was assigned to an Si—O—Al mode based on Ge substitutions for Si. A bromosodalite band at 200 cm−1 is assigned to an Na—cage vibration based on previous H2annealing studies and chemical substitution of Ge for Si, Ga for Al and Cl and I for Br. A 107 cm−1 band is the Na—Br related vibration, and substitution of 100% Cl for Br moved this band to 111 cm−1, H2 and vacuum-annealing studies show a correlation between the amount of Br removed from bromosodalite during annealing and the area of the 107 cm−1 band. A band at 68 cm−1 is the Na—Br mode based on 100% substitution of Cl for Br. Coloration studies in the 50–150 cm−1 region show no changes attributable to F-center formation." @default.
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- W2079403548 date "1985-05-01" @default.
- W2079403548 modified "2023-09-27" @default.
- W2079403548 title "A far-infrared investigation of cathodochromic sodalite" @default.
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- W2079403548 doi "https://doi.org/10.1016/0020-0891(85)90026-0" @default.
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