Matches in SemOpenAlex for { <https://semopenalex.org/work/W2079405764> ?p ?o ?g. }
Showing items 1 to 97 of
97
with 100 items per page.
- W2079405764 endingPage "51" @default.
- W2079405764 startingPage "39" @default.
- W2079405764 abstract "We have used an RF sputter source to produce gas-phase copper dimer molecules for study with laser-induced fluorescence spectroscopy. Rotationally resolved spectra of transitions from the electronic ground (X) state to the A, B, C, G, and J states have been obtained. Previous rotational analyses of the X, A, and B states are confirmed. Analysis of the X–C spectrum shows the C state to have Π(Ω=1) symmetry, and a bond length of 2.26 Å. Its vibrational constants are refined slightly. The J state has a bond length of 2.15 Å, and shows evidence of extensive perturbation. Emission lifetimes at the bandheads of its lowest two vibrational states are 80 ns. Franck–Condon factors for the X–C and X–J transitions have also been obtained. The new J state bond length supports conclusions drawn from a recently obtained photoelectron spectrum of Cu2: the cation ground state indeed corresponds to loss of a 4sσ electron, and the excited state is due to removal of a 3d electron. Bond strengths and distances in the various states of the neutral are rationalized in terms of 4sσ bonding orbitals and nonbonding (slightly repelling) 3d cores; creation of a 3d vacancy allows 3d shell bonding to occur, increasing bond strengths and vibrational frequencies slightly." @default.
- W2079405764 created "2016-06-24" @default.
- W2079405764 creator A5007692196 @default.
- W2079405764 creator A5046966182 @default.
- W2079405764 date "1991-01-01" @default.
- W2079405764 modified "2023-09-26" @default.
- W2079405764 title "Rotationally resolved dicopper (Cu<sub>2</sub>) laser‐induced fluorescence spectra" @default.
- W2079405764 cites W1217826182 @default.
- W2079405764 cites W1583156618 @default.
- W2079405764 cites W1965603563 @default.
- W2079405764 cites W1967121333 @default.
- W2079405764 cites W1971708700 @default.
- W2079405764 cites W1976785556 @default.
- W2079405764 cites W1977904382 @default.
- W2079405764 cites W1985268540 @default.
- W2079405764 cites W1986153230 @default.
- W2079405764 cites W2001343203 @default.
- W2079405764 cites W2004029093 @default.
- W2079405764 cites W2013822843 @default.
- W2079405764 cites W2018235196 @default.
- W2079405764 cites W2030678851 @default.
- W2079405764 cites W2033471517 @default.
- W2079405764 cites W2047699519 @default.
- W2079405764 cites W2058311036 @default.
- W2079405764 cites W2060052077 @default.
- W2079405764 cites W2078516191 @default.
- W2079405764 cites W2086959068 @default.
- W2079405764 cites W2089944279 @default.
- W2079405764 cites W2094511377 @default.
- W2079405764 cites W2949446017 @default.
- W2079405764 cites W3005257074 @default.
- W2079405764 cites W4230046747 @default.
- W2079405764 cites W4380905040 @default.
- W2079405764 cites W73933404 @default.
- W2079405764 doi "https://doi.org/10.1063/1.460355" @default.
- W2079405764 hasPublicationYear "1991" @default.
- W2079405764 type Work @default.
- W2079405764 sameAs 2079405764 @default.
- W2079405764 citedByCount "40" @default.
- W2079405764 countsByYear W20794057642012 @default.
- W2079405764 countsByYear W20794057642014 @default.
- W2079405764 countsByYear W20794057642015 @default.
- W2079405764 countsByYear W20794057642017 @default.
- W2079405764 countsByYear W20794057642018 @default.
- W2079405764 countsByYear W20794057642019 @default.
- W2079405764 countsByYear W20794057642021 @default.
- W2079405764 countsByYear W20794057642022 @default.
- W2079405764 crossrefType "journal-article" @default.
- W2079405764 hasAuthorship W2079405764A5007692196 @default.
- W2079405764 hasAuthorship W2079405764A5046966182 @default.
- W2079405764 hasConcept C121332964 @default.
- W2079405764 hasConcept C1276947 @default.
- W2079405764 hasConcept C155860418 @default.
- W2079405764 hasConcept C178790620 @default.
- W2079405764 hasConcept C181500209 @default.
- W2079405764 hasConcept C184779094 @default.
- W2079405764 hasConcept C185592680 @default.
- W2079405764 hasConcept C32891209 @default.
- W2079405764 hasConcept C32909587 @default.
- W2079405764 hasConcept C41999313 @default.
- W2079405764 hasConcept C4839761 @default.
- W2079405764 hasConcept C62520636 @default.
- W2079405764 hasConcept C69523127 @default.
- W2079405764 hasConceptScore W2079405764C121332964 @default.
- W2079405764 hasConceptScore W2079405764C1276947 @default.
- W2079405764 hasConceptScore W2079405764C155860418 @default.
- W2079405764 hasConceptScore W2079405764C178790620 @default.
- W2079405764 hasConceptScore W2079405764C181500209 @default.
- W2079405764 hasConceptScore W2079405764C184779094 @default.
- W2079405764 hasConceptScore W2079405764C185592680 @default.
- W2079405764 hasConceptScore W2079405764C32891209 @default.
- W2079405764 hasConceptScore W2079405764C32909587 @default.
- W2079405764 hasConceptScore W2079405764C41999313 @default.
- W2079405764 hasConceptScore W2079405764C4839761 @default.
- W2079405764 hasConceptScore W2079405764C62520636 @default.
- W2079405764 hasConceptScore W2079405764C69523127 @default.
- W2079405764 hasIssue "1" @default.
- W2079405764 hasLocation W20794057641 @default.
- W2079405764 hasOpenAccess W2079405764 @default.
- W2079405764 hasPrimaryLocation W20794057641 @default.
- W2079405764 hasRelatedWork W1017473139 @default.
- W2079405764 hasRelatedWork W1613483563 @default.
- W2079405764 hasRelatedWork W1926570229 @default.
- W2079405764 hasRelatedWork W1967123339 @default.
- W2079405764 hasRelatedWork W1996227499 @default.
- W2079405764 hasRelatedWork W1999339278 @default.
- W2079405764 hasRelatedWork W2044129740 @default.
- W2079405764 hasRelatedWork W2092752668 @default.
- W2079405764 hasRelatedWork W2241422244 @default.
- W2079405764 hasRelatedWork W2266149758 @default.
- W2079405764 hasVolume "94" @default.
- W2079405764 isParatext "false" @default.
- W2079405764 isRetracted "false" @default.
- W2079405764 magId "2079405764" @default.
- W2079405764 workType "article" @default.