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- W2079407633 abstract "Abstract NaTe has been synthesized in a two-step reaction from the elements in liquid ammonia at −70 °C, followed by an annealing period of two weeks at 300 °C. The compound that results is a bronze-coloured product with metallic lustre. NaTe crystallizes in the orthorhombic form, space group Pbcn (No. 60), Z = 12. The cell constants are as follows: a = 15.892(9) A , b = 9.947(2) A , c = 9.179(2) A . The formula should be written as Na6-Te(Te5) according to the characteristic features of the structure. The anionic part of the structure consists of isolated Te2− ions as well as Z-shaped Te54− groups, the latter being isoelectronic and identical in shape with I3Cl2+. The previously unknown Te54− unit is compared with similar groups occurring in other tellurium-rich tellurides." @default.
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- W2079407633 date "1985-07-01" @default.
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- W2079407633 title "The crystal structure of NaTe and its relationship to tellurium-rich tellurides" @default.
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- W2079407633 doi "https://doi.org/10.1016/0022-5088(85)90062-1" @default.
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