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- W2079409140 abstract "Abstract The binding isotherms of dodecylpyridinium (DP + ) cations and dodecyltrimethylammonium (DTA + ) cations with alternating copolymers of maleic acid with ethylene (MAE), ethyl vinyl ether (MAEVE), styrene (MASt) and indene (MAIn) were determined in the presence of NaCl by using a potentiometric technique based on surfactant-ion-selective solid-state membrane electrodes. Surfactant binding by MAE shows only single-step isotherms. In contrast, MAEVE, MASt and MAIn show a two-step binding isotherm. The first binding step (the stronger binding mode) in the isotherms is due to the interaction of the surfactant with a combined polyion site containing a charged and a hydrophobic group. The second binding step (the weaker binding mode) is always in the same free surfactant concentration region as for the isotherms with MAE at corresponding NaCl concentrations, indicating a binding mainly through electrostatic interaction. The standard free energies of the binding were calculated for MAEVE, MASt and MAIn from the isotherms obtained and compared with the standard free energy for MAE to examine the thermodynamic contribution of the hydrophobic side chains to the binding process." @default.
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- W2079409140 title "The binding of cationic surfactants by hydrophobic alternating copolymers of maleic acid" @default.
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