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- W2079409400 abstract "Proton-bound dimers can be generated between the stable free radical, 2,2,6,6-tetramethyl-l-piperidinyloxy (TEMPO), and various reference compounds in a chemical ionization source. The individual mass-selected dimers dissociate upon collision to yield the protonated monomers as the only product ions. From their relative abundances the kinetic method yields a value of 209.5 ± 1.0 kcal mol−1 for the proton affinity of the TEMPO radical. The proton affinity is compared to that of m-methylphenoxyl and other oxy radicals." @default.
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- W2079409400 date "1995-12-01" @default.
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- W2079409400 title "Proton affinity of the stable free radical 2,2,6,6-tetramethyl-l-piperidinyloxy measured by the kinetic method" @default.
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- W2079409400 doi "https://doi.org/10.1016/0168-1176(95)04308-4" @default.
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