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- W2079413504 abstract "Die Molekülstrukturen der Komplexe [(NO)2FeP(C6H5)2]2 (1), [(NO) 2FeP(CH3)2]2 (2) und [CO(NO)CoP(C6H5)2]2 (4) wurden kristallographisch bestimmt. Sie erlauben zusammen mit Literaturangaben die Diskussion der Metall-Metall-Bindung in zwei Komplexreihen. In der Reihe [L2MP(C6H5)2]2 mit L2M(NO) 2Fe, CO(NO)Co, (CO) 2Ni (1,4,5) steuert der elektronische Einfluß der Liganden L die Metall-Metall-Bindungslängen. In der Reihe [NO) 2FePR2]2mit RC6 H5, CH3, CF3 (1,2,3) bewirkt die Variation der Phosphorsubstituenten R nur unwesentliche Veränderungen des Molekülgerüstes. Stereochemistry of the Metal-Metal Bond. The Structures of three Complexes of the Type [L2MPR2]2 The molecular structures of the complexes [(NO)2FeP(C6H5)2]2 (2), and [CO(NO)CoP(C6H5)2]2 (4) were determined crystallographically. Together with literature data they allow the discussion of the metal-metal bonding in two series of complexes. In the series [L2M P(C6H5)2]2 with L2M(NO)2Fe, CO(NO)2Co, (CO)2Ni (1,4,5) the metal-metal-bond lengths are controlled by the electronic influence of the ligands L. In the series [(NO)2FePR2]2 with RC6H5, CH3, CF3 (1,2,3) the variation of the phosphorus substituents generates only minor changes of the molecular framework." @default.
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- W2079413504 date "1979-05-01" @default.
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- W2079413504 title "Stereochemie der Metall‐Metall‐Bindung. Die Strukturen dreier Komplexe des Typs [L <sub>2</sub> MPR <sub>2</sub> ] <sub>2</sub>" @default.
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- W2079413504 doi "https://doi.org/10.1002/cber.19791120513" @default.
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