FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2079415787> ?p ?o ?g. }

• W2079415787 abstract "Recent simulations of crystal nucleation from a compressed liquid of oppositely charged colloids show that the natural Brownian dynamics results in nuclei of a charge-disordered FCC (DFCC) solid whereas artificially accelerated dynamics with charge swap moves result in charge-ordered nuclei of a CsCl phase. These results were interpreted as a breakdown of the quasiequilibrium assumption for precritical nuclei. We use structure-specific nucleus size coordinates for the CsCl and DFCC structures and equilibrium based sampling methods to understand the dynamical effects on structure selectivity in this system. Nonequilibrium effects observed in previous simulations emerge from a diffusion tensor that dramatically changes when charge swap moves are used. Without the charge swap moves diffusion is strongly anisotropic with very slow motion along the charge-ordered CsCl axis and faster motion along the DFCC axis. Kramers–Langer–Berezhkovskii–Szabo theory predicts that under the realistic dynamics, the diffusion anisotropy shifts the current toward the DFCC axis. The diffusion tensor also varies with location on the free energy landscape. A numerical calculation of the current field with a diffusion tensor that depends on the location in the free energy landscape exacerbates the extent to which the current is skewed toward DFCC structures. Our analysis confirms that quasiequilibrium theories based on equilibrium properties can explain the nonequilibrium behavior of this system. Our analysis also shows that using a structure-specific nucleus size coordinate for each possible nucleation product can provide mechanistic insight on selectivity and competition between nucleation pathways." @default.
• W2079415787 created "2016-06-24" @default.
• W2079415787 creator A5003451698 @default.
• W2079415787 date "2009-12-22" @default.
• W2079415787 modified "2023-09-23" @default.
• W2079415787 title "Competing nucleation pathways in a mixture of oppositely charged colloids: Out-of-equilibrium nucleation revisited" @default.
• W2079415787 cites W1484646597 @default.
• W2079415787 cites W1967722756 @default.
• W2079415787 cites W1968640111 @default.
• W2079415787 cites W1969714929 @default.
• W2079415787 cites W1976998887 @default.
• W2079415787 cites W1981779898 @default.
• W2079415787 cites W1991240354 @default.
• W2079415787 cites W1991861508 @default.
• W2079415787 cites W1993846714 @default.
• W2079415787 cites W1994633233 @default.
• W2079415787 cites W1995860143 @default.
• W2079415787 cites W2004358890 @default.
• W2079415787 cites W2006761670 @default.
• W2079415787 cites W2011242225 @default.
• W2079415787 cites W2012306680 @default.
• W2079415787 cites W2012510807 @default.
• W2079415787 cites W2012901551 @default.
• W2079415787 cites W2013020529 @default.
• W2079415787 cites W2015669922 @default.
• W2079415787 cites W2023036648 @default.
• W2079415787 cites W2029955311 @default.
• W2079415787 cites W2031952899 @default.
• W2079415787 cites W2032043013 @default.
• W2079415787 cites W2032472136 @default.
• W2079415787 cites W2033858596 @default.
• W2079415787 cites W2038973702 @default.
• W2079415787 cites W2044472996 @default.
• W2079415787 cites W2047495388 @default.
• W2079415787 cites W2049738344 @default.
• W2079415787 cites W2051039246 @default.
• W2079415787 cites W2051116535 @default.
• W2079415787 cites W2054959591 @default.
• W2079415787 cites W2064104154 @default.
• W2079415787 cites W2064556178 @default.
• W2079415787 cites W2070501205 @default.
• W2079415787 cites W2071899323 @default.
• W2079415787 cites W2073705013 @default.
• W2079415787 cites W2073885652 @default.
• W2079415787 cites W2074768610 @default.
• W2079415787 cites W2082592769 @default.
• W2079415787 cites W2085266415 @default.
• W2079415787 cites W2088544928 @default.
• W2079415787 cites W2092130625 @default.
• W2079415787 cites W2092144432 @default.
• W2079415787 cites W2092879669 @default.
• W2079415787 cites W2095884427 @default.
• W2079415787 cites W2096330665 @default.
• W2079415787 cites W2098689615 @default.
• W2079415787 cites W2108149882 @default.
• W2079415787 cites W2113947977 @default.
• W2079415787 cites W2115527815 @default.
• W2079415787 cites W2124349166 @default.
• W2079415787 cites W2139091534 @default.
• W2079415787 cites W2140373682 @default.
• W2079415787 cites W2142996228 @default.
• W2079415787 cites W2146019686 @default.
• W2079415787 cites W2151438634 @default.
• W2079415787 cites W2155430461 @default.
• W2079415787 cites W2156869304 @default.
• W2079415787 cites W2161558954 @default.
• W2079415787 cites W2165848788 @default.
• W2079415787 cites W2166500477 @default.
• W2079415787 cites W2168100752 @default.
• W2079415787 cites W2168175927 @default.
• W2079415787 cites W2168498338 @default.
• W2079415787 cites W3105943282 @default.
• W2079415787 doi "https://doi.org/10.1063/1.3271024" @default.
• W2079415787 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20059050" @default.
• W2079415787 hasPublicationYear "2009" @default.
• W2079415787 type Work @default.
• W2079415787 sameAs 2079415787 @default.
• W2079415787 citedByCount "63" @default.
• W2079415787 countsByYear W20794157872012 @default.
• W2079415787 countsByYear W20794157872013 @default.
• W2079415787 countsByYear W20794157872014 @default.
• W2079415787 countsByYear W20794157872015 @default.
• W2079415787 countsByYear W20794157872016 @default.
• W2079415787 countsByYear W20794157872017 @default.
• W2079415787 countsByYear W20794157872018 @default.
• W2079415787 countsByYear W20794157872019 @default.
• W2079415787 countsByYear W20794157872020 @default.
• W2079415787 countsByYear W20794157872021 @default.
• W2079415787 countsByYear W20794157872022 @default.
• W2079415787 countsByYear W20794157872023 @default.
• W2079415787 crossrefType "journal-article" @default.
• W2079415787 hasAuthorship W2079415787A5003451698 @default.
• W2079415787 hasConcept C112401455 @default.
• W2079415787 hasConcept C119621388 @default.
• W2079415787 hasConcept C121332964 @default.
• W2079415787 hasConcept C121864883 @default.
• W2079415787 hasConcept C159467904 @default.
• W2079415787 hasConcept C185592680 @default.
• W2079415787 hasConcept C26873012 @default.
• W2079415787 hasConcept C2780393986 @default.

• next