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- W2079423207 startingPage "1884" @default.
- W2079423207 abstract "trans-2-p-Phenylcyclohexyl p-toluenesulfonate acetolyzes (75°C), at one-eighth of the rate of cyclohexyl p-toluenesulfonate, and one-sixteenth times smaller than that of the cis isomer. trans-2-p-Anisylcyclohexyl p-toluenesulfonate acetolyzes (75°C) much the same as cyclohexyl p-toluenesulfonate, and one-third times smaller than that of the cis isomer. Thus, the slow rate of the trans isomers cannot be interpreted in term of significant phenyl and p-anisylparticipation. This may be due to high cost in energy required to place the aryl group in the axial position where it would be in a favorable position to participate. However, it is noteworthy that the acetolysis of trans-2-p-anisylcyclohexyl p-toluenesulfonate gave trans-2-p-anisylcyclohexyl acetate in 70% yield, which had retention of configuration. The mechanism of this reaction is discussed. The greater reactivities of cis isomers are interpreted in terms of E2 type elimination involving nucleophilic participation by the solvent as well as 2-alkylcyc..." @default.
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- W2079423207 date "1968-08-01" @default.
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- W2079423207 title "Solvolysis ofcisandtrans2-Cyclohexylcyclohexyl, 2-Phenylcyclohexyl and 2-p-Anisylcyclohexylp-Toluenesulfonate" @default.
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