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- W2079427335 abstract "Abstract A kinetic method is proposed for the determination of uranium(VI), based on its catalytic action on the decomposition of hydrogen peroxide in alkaline media. The reaction rate was followed by the stopped-flow spectrophotometric technique. On the basis of data obtained by kinetic investigations, the kinetic expression was postulated and the conditional rate constant was calculated. The method developed can be applied to the determination of uranium(VI) by the tangent method in the concentration range from 0.8 to 6.4 μg/ml. The method is selective since it enables the determination of uranium(VI) in the presence of 50–1000 times higher concentrations of NH 4 (I), Ca(II), Al(III), Fe(III), Mo(VI), phosphate, sulfate, and fluoride. The method is applied for the determination of uranium in phosphoric acid and phosphate ores." @default.
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- W2079427335 date "1988-06-01" @default.
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- W2079427335 title "A novel kinetic method for the determination of uranium(VI) based on the decomposition of hydrogen peroxide" @default.
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- W2079427335 doi "https://doi.org/10.1016/0026-265x(88)90135-x" @default.
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