FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2079430689> ?p ?o ?g. }

• W2079430689 endingPage "162" @default.
• W2079430689 startingPage "154" @default.
• W2079430689 abstract "DFT calculations were performed on the thermal reactions of chlorpropham 1, a carbamate pesticide and plant growth regulator frequently used in the storage of potatoes. At the conditions normally used in applying 1 (injection of a methanolic solution of 1 into a hot air stream, T ∼ 500 °C), both ester pyrolysis of 1 and a methanol-or water-catalysed isocyanate cleavage are expected to proceed rapidly (lifetime of 1 less than a second). In both reactions, the final reaction product will be toxic and carcinogenic m-chloroaniline 2. Matrix-isolation experiments indicate that 1 undergoes thermal decay at temperatures as low as 250 °C. Up to temperatures of ca. 500 °C, formation of m-chlorophenylisocyanate 4 and isopropanol was the predominant reaction observed, while formation of propene, CO2, and m-chloroaniline 2 was the most important reaction channel at higher pyrolysis temperatures. m-Chlorophenyl carbamic acid 3 could not be observed. The results indicate that at lower temperatures, 1 decays exclusively via isocyanate cleavage of 1, provided that traces of catalytic water or other protic compounds are present. At higher temperatures, ester cleavage of 1 becomes competitive and outweighs the isocyanate cleavage by a factor of ca. 10:1." @default.
• W2079430689 created "2016-06-24" @default.
• W2079430689 creator A5048100143 @default.
• W2079430689 creator A5052891474 @default.
• W2079430689 creator A5072616753 @default.
• W2079430689 creator A5081063403 @default.
• W2079430689 date "2013-02-01" @default.
• W2079430689 modified "2023-09-26" @default.
• W2079430689 title "Mechanisms of the thermal decay of chlorpropham" @default.
• W2079430689 cites W1965127347 @default.
• W2079430689 cites W1981183522 @default.
• W2079430689 cites W1984110977 @default.
• W2079430689 cites W1986875494 @default.
• W2079430689 cites W1993077801 @default.
• W2079430689 cites W1997151511 @default.
• W2079430689 cites W2007739944 @default.
• W2079430689 cites W2009739045 @default.
• W2079430689 cites W2016737982 @default.
• W2079430689 cites W2019859265 @default.
• W2079430689 cites W2027075337 @default.
• W2079430689 cites W2029791068 @default.
• W2079430689 cites W2035871305 @default.
• W2079430689 cites W2041261104 @default.
• W2079430689 cites W2049013587 @default.
• W2079430689 cites W2072951441 @default.
• W2079430689 cites W2075556809 @default.
• W2079430689 cites W2080286292 @default.
• W2079430689 cites W2091015884 @default.
• W2079430689 cites W2119148583 @default.
• W2079430689 cites W2127413733 @default.
• W2079430689 cites W2135838125 @default.
• W2079430689 cites W2139242466 @default.
• W2079430689 cites W2140622780 @default.
• W2079430689 cites W2154771600 @default.
• W2079430689 cites W2165388389 @default.
• W2079430689 cites W2166520502 @default.
• W2079430689 cites W2171445884 @default.
• W2079430689 cites W2319342026 @default.
• W2079430689 cites W2329951993 @default.
• W2079430689 cites W2334455629 @default.
• W2079430689 cites W2950656254 @default.
• W2079430689 cites W320862611 @default.
• W2079430689 cites W4361807724 @default.
• W2079430689 cites W46929847 @default.
• W2079430689 doi "https://doi.org/10.1016/j.jhazmat.2012.12.003" @default.
• W2079430689 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23295769" @default.
• W2079430689 hasPublicationYear "2013" @default.
• W2079430689 type Work @default.
• W2079430689 sameAs 2079430689 @default.
• W2079430689 citedByCount "10" @default.
• W2079430689 countsByYear W20794306892014 @default.
• W2079430689 countsByYear W20794306892017 @default.
• W2079430689 countsByYear W20794306892018 @default.
• W2079430689 countsByYear W20794306892019 @default.
• W2079430689 countsByYear W20794306892020 @default.
• W2079430689 crossrefType "journal-article" @default.
• W2079430689 hasAuthorship W2079430689A5048100143 @default.
• W2079430689 hasAuthorship W2079430689A5052891474 @default.
• W2079430689 hasAuthorship W2079430689A5072616753 @default.
• W2079430689 hasAuthorship W2079430689A5081063403 @default.
• W2079430689 hasConcept C127413603 @default.
• W2079430689 hasConcept C161790260 @default.
• W2079430689 hasConcept C175156509 @default.
• W2079430689 hasConcept C178790620 @default.
• W2079430689 hasConcept C185592680 @default.
• W2079430689 hasConcept C187320778 @default.
• W2079430689 hasConcept C2777954637 @default.
• W2079430689 hasConcept C2779303437 @default.
• W2079430689 hasConcept C2779319593 @default.
• W2079430689 hasConcept C2779578285 @default.
• W2079430689 hasConcept C2779607525 @default.
• W2079430689 hasConcept C2780534471 @default.
• W2079430689 hasConcept C36759035 @default.
• W2079430689 hasConcept C43369102 @default.
• W2079430689 hasConceptScore W2079430689C127413603 @default.
• W2079430689 hasConceptScore W2079430689C161790260 @default.
• W2079430689 hasConceptScore W2079430689C175156509 @default.
• W2079430689 hasConceptScore W2079430689C178790620 @default.
• W2079430689 hasConceptScore W2079430689C185592680 @default.
• W2079430689 hasConceptScore W2079430689C187320778 @default.
• W2079430689 hasConceptScore W2079430689C2777954637 @default.
• W2079430689 hasConceptScore W2079430689C2779303437 @default.
• W2079430689 hasConceptScore W2079430689C2779319593 @default.
• W2079430689 hasConceptScore W2079430689C2779578285 @default.
• W2079430689 hasConceptScore W2079430689C2779607525 @default.
• W2079430689 hasConceptScore W2079430689C2780534471 @default.
• W2079430689 hasConceptScore W2079430689C36759035 @default.
• W2079430689 hasConceptScore W2079430689C43369102 @default.
• W2079430689 hasLocation W20794306891 @default.
• W2079430689 hasLocation W20794306892 @default.
• W2079430689 hasOpenAccess W2079430689 @default.
• W2079430689 hasPrimaryLocation W20794306891 @default.
• W2079430689 hasRelatedWork W1536379448 @default.
• W2079430689 hasRelatedWork W1975492452 @default.
• W2079430689 hasRelatedWork W1994159282 @default.
• W2079430689 hasRelatedWork W2011696161 @default.
• W2079430689 hasRelatedWork W2163470283 @default.
• W2079430689 hasRelatedWork W2341011754 @default.

• next