FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2079431607> ?p ?o ?g. }

• W2079431607 endingPage "4267" @default.
• W2079431607 startingPage "4262" @default.
• W2079431607 abstract "The reactions of the phthalimide N-oxyl (PINO) radical with several hydrocarbons having different C−H bond dissociation energies (BDEs) were investigated in HOAc at 25 °C. The slope of the Evans−Polanyi plot is 0.38, which indicates that the reactions are mildly exothermic or almost thermoneutral. This finding is supported by the O−H BDE of N-hydroxyphthalimide (NHPI), 375 ± 10 kJ mol-1, obtained by means of a thermodynamic cycle. The observed kinetic isotope effects (KIEs) are related to the reaction free-energy changes, which can be explained by a Marcus-type equation. The comparison of the PINO radical reactions with analogous hydrogen atom abstraction reactions of the dibromide radical implies that HBr2• reactions are more exothermic than the PINO radical reactions. This factor is put forth to explain the different KIEs." @default.
• W2079431607 created "2016-06-24" @default.
• W2079431607 creator A5062153607 @default.
• W2079431607 creator A5078861003 @default.
• W2079431607 creator A5084394443 @default.
• W2079431607 date "2003-05-01" @default.
• W2079431607 modified "2023-10-07" @default.
• W2079431607 title "Kinetic Study of the Phthalimide <i>N</i>-Oxyl (PINO) Radical in Acetic Acid. Hydrogen Abstraction from C−H Bonds and Evaluation of O−H Bond Dissociation Energy of <i>N</i>-Hydroxyphthalimide" @default.
• W2079431607 cites W1989051182 @default.
• W2079431607 cites W2004752165 @default.
• W2079431607 cites W2008998559 @default.
• W2079431607 cites W2017818169 @default.
• W2079431607 cites W2018341062 @default.
• W2079431607 cites W2038068294 @default.
• W2079431607 cites W2045095645 @default.
• W2079431607 cites W2053772394 @default.
• W2079431607 cites W2061554029 @default.
• W2079431607 cites W2087049043 @default.
• W2079431607 cites W2091396348 @default.
• W2079431607 cites W2104559955 @default.
• W2079431607 cites W2113310023 @default.
• W2079431607 cites W2126111554 @default.
• W2079431607 cites W3004681674 @default.
• W2079431607 cites W4236909298 @default.
• W2079431607 doi "https://doi.org/10.1021/jp0276193" @default.
• W2079431607 hasPublicationYear "2003" @default.
• W2079431607 type Work @default.
• W2079431607 sameAs 2079431607 @default.
• W2079431607 citedByCount "101" @default.
• W2079431607 countsByYear W20794316072012 @default.
• W2079431607 countsByYear W20794316072013 @default.
• W2079431607 countsByYear W20794316072014 @default.
• W2079431607 countsByYear W20794316072015 @default.
• W2079431607 countsByYear W20794316072016 @default.
• W2079431607 countsByYear W20794316072017 @default.
• W2079431607 countsByYear W20794316072018 @default.
• W2079431607 countsByYear W20794316072019 @default.
• W2079431607 countsByYear W20794316072021 @default.
• W2079431607 countsByYear W20794316072022 @default.
• W2079431607 countsByYear W20794316072023 @default.
• W2079431607 crossrefType "journal-article" @default.
• W2079431607 hasAuthorship W2079431607A5062153607 @default.
• W2079431607 hasAuthorship W2079431607A5078861003 @default.
• W2079431607 hasAuthorship W2079431607A5084394443 @default.
• W2079431607 hasConcept C102931765 @default.
• W2079431607 hasConcept C121332964 @default.
• W2079431607 hasConcept C139066938 @default.
• W2079431607 hasConcept C147597530 @default.
• W2079431607 hasConcept C147789679 @default.
• W2079431607 hasConcept C155647269 @default.
• W2079431607 hasConcept C178790620 @default.
• W2079431607 hasConcept C185592680 @default.
• W2079431607 hasConcept C2776640939 @default.
• W2079431607 hasConcept C2778522978 @default.
• W2079431607 hasConcept C2780263894 @default.
• W2079431607 hasConcept C45119746 @default.
• W2079431607 hasConcept C58364064 @default.
• W2079431607 hasConcept C62396407 @default.
• W2079431607 hasConcept C62520636 @default.
• W2079431607 hasConcept C69928629 @default.
• W2079431607 hasConcept C75473681 @default.
• W2079431607 hasConcept C81022585 @default.
• W2079431607 hasConcept C95121573 @default.
• W2079431607 hasConceptScore W2079431607C102931765 @default.
• W2079431607 hasConceptScore W2079431607C121332964 @default.
• W2079431607 hasConceptScore W2079431607C139066938 @default.
• W2079431607 hasConceptScore W2079431607C147597530 @default.
• W2079431607 hasConceptScore W2079431607C147789679 @default.
• W2079431607 hasConceptScore W2079431607C155647269 @default.
• W2079431607 hasConceptScore W2079431607C178790620 @default.
• W2079431607 hasConceptScore W2079431607C185592680 @default.
• W2079431607 hasConceptScore W2079431607C2776640939 @default.
• W2079431607 hasConceptScore W2079431607C2778522978 @default.
• W2079431607 hasConceptScore W2079431607C2780263894 @default.
• W2079431607 hasConceptScore W2079431607C45119746 @default.
• W2079431607 hasConceptScore W2079431607C58364064 @default.
• W2079431607 hasConceptScore W2079431607C62396407 @default.
• W2079431607 hasConceptScore W2079431607C62520636 @default.
• W2079431607 hasConceptScore W2079431607C69928629 @default.
• W2079431607 hasConceptScore W2079431607C75473681 @default.
• W2079431607 hasConceptScore W2079431607C81022585 @default.
• W2079431607 hasConceptScore W2079431607C95121573 @default.
• W2079431607 hasIssue "21" @default.
• W2079431607 hasLocation W20794316071 @default.
• W2079431607 hasOpenAccess W2079431607 @default.
• W2079431607 hasPrimaryLocation W20794316071 @default.
• W2079431607 hasRelatedWork W1964117855 @default.
• W2079431607 hasRelatedWork W1970814444 @default.
• W2079431607 hasRelatedWork W1975256021 @default.
• W2079431607 hasRelatedWork W1993596795 @default.
• W2079431607 hasRelatedWork W2065682390 @default.
• W2079431607 hasRelatedWork W2074304097 @default.
• W2079431607 hasRelatedWork W2079887392 @default.
• W2079431607 hasRelatedWork W2105609847 @default.
• W2079431607 hasRelatedWork W2615245087 @default.
• W2079431607 hasRelatedWork W4246414068 @default.
• W2079431607 hasVolume "107" @default.
• W2079431607 isParatext "false" @default.

• next