Matches in SemOpenAlex for { <https://semopenalex.org/work/W2079432215> ?p ?o ?g. }
Showing items 1 to 93 of
93
with 100 items per page.
- W2079432215 endingPage "18" @default.
- W2079432215 startingPage "13" @default.
- W2079432215 abstract "Abstract Poly dimethyl siloxane (PDMS) membranes show potential for the separation of carbon dioxide from hydrogen in syngas applications due to their strong affinity for CO 2 . The Flory–Rehner theory of mixing enables the sorption of gases within such a rubbery membrane to be modeled, as long as the Flory–Huggins interaction parameters are known. In this work, mixed gas permeation experiments are used to determine interaction parameters for a range of relevant gas pairs. For the N 2 –H 2 system, the mixed gas performance is comparable to pure gas measurements and indicates that H 2 does not interfere with the permeation of N 2 through the membrane. In contrast, for the CO 2 –H 2 system, the CO 2 permeability falls with increasing H 2 partial pressure, attributed to competitive sorption. The effect of a typical hydrocarbon impurity, toluene, upon CO 2 and N 2 permeability through PDMS was also measured. The addition of this aromatic hydrocarbon caused significant polymer swelling, which required solubility modeling with the Flory–Rehner model. A concentration dependent diffusivity was also required to fit the permeation data. The parameters determined from the laboratory experiments were used to model pilot plant results for a PDMS membrane separating CO 2 from syngas, as part of the CO2CRC Mulgrave Project. It was found that the model could effectively predict experimental CO 2 , N 2 and H 2 permeabilities." @default.
- W2079432215 created "2016-06-24" @default.
- W2079432215 creator A5012386870 @default.
- W2079432215 creator A5048935819 @default.
- W2079432215 creator A5076923063 @default.
- W2079432215 date "2013-09-01" @default.
- W2079432215 modified "2023-09-25" @default.
- W2079432215 title "Modeling syngas permeation through a poly dimethyl siloxane membrane by Flory–Rehner theory" @default.
- W2079432215 cites W1963842023 @default.
- W2079432215 cites W1964536978 @default.
- W2079432215 cites W1973694328 @default.
- W2079432215 cites W1979935038 @default.
- W2079432215 cites W1993854666 @default.
- W2079432215 cites W1997572975 @default.
- W2079432215 cites W2002004627 @default.
- W2079432215 cites W2002899682 @default.
- W2079432215 cites W2003943899 @default.
- W2079432215 cites W2010565779 @default.
- W2079432215 cites W2015846069 @default.
- W2079432215 cites W2016268102 @default.
- W2079432215 cites W2023721964 @default.
- W2079432215 cites W2026675230 @default.
- W2079432215 cites W2032637986 @default.
- W2079432215 cites W2033089091 @default.
- W2079432215 cites W2045538371 @default.
- W2079432215 cites W2051405992 @default.
- W2079432215 cites W2054278185 @default.
- W2079432215 cites W2066666420 @default.
- W2079432215 cites W2068276685 @default.
- W2079432215 cites W2079842516 @default.
- W2079432215 cites W2136057251 @default.
- W2079432215 cites W2141189987 @default.
- W2079432215 cites W2148837678 @default.
- W2079432215 doi "https://doi.org/10.1016/j.seppur.2013.05.006" @default.
- W2079432215 hasPublicationYear "2013" @default.
- W2079432215 type Work @default.
- W2079432215 sameAs 2079432215 @default.
- W2079432215 citedByCount "4" @default.
- W2079432215 countsByYear W20794322152014 @default.
- W2079432215 countsByYear W20794322152015 @default.
- W2079432215 countsByYear W20794322152018 @default.
- W2079432215 crossrefType "journal-article" @default.
- W2079432215 hasAuthorship W2079432215A5012386870 @default.
- W2079432215 hasAuthorship W2079432215A5048935819 @default.
- W2079432215 hasAuthorship W2079432215A5076923063 @default.
- W2079432215 hasConcept C126348684 @default.
- W2079432215 hasConcept C127413603 @default.
- W2079432215 hasConcept C161790260 @default.
- W2079432215 hasConcept C178790620 @default.
- W2079432215 hasConcept C185592680 @default.
- W2079432215 hasConcept C188027245 @default.
- W2079432215 hasConcept C192562407 @default.
- W2079432215 hasConcept C194439259 @default.
- W2079432215 hasConcept C2776139660 @default.
- W2079432215 hasConcept C41625074 @default.
- W2079432215 hasConcept C42360764 @default.
- W2079432215 hasConcept C50670333 @default.
- W2079432215 hasConcept C521977710 @default.
- W2079432215 hasConcept C55493867 @default.
- W2079432215 hasConceptScore W2079432215C126348684 @default.
- W2079432215 hasConceptScore W2079432215C127413603 @default.
- W2079432215 hasConceptScore W2079432215C161790260 @default.
- W2079432215 hasConceptScore W2079432215C178790620 @default.
- W2079432215 hasConceptScore W2079432215C185592680 @default.
- W2079432215 hasConceptScore W2079432215C188027245 @default.
- W2079432215 hasConceptScore W2079432215C192562407 @default.
- W2079432215 hasConceptScore W2079432215C194439259 @default.
- W2079432215 hasConceptScore W2079432215C2776139660 @default.
- W2079432215 hasConceptScore W2079432215C41625074 @default.
- W2079432215 hasConceptScore W2079432215C42360764 @default.
- W2079432215 hasConceptScore W2079432215C50670333 @default.
- W2079432215 hasConceptScore W2079432215C521977710 @default.
- W2079432215 hasConceptScore W2079432215C55493867 @default.
- W2079432215 hasLocation W20794322151 @default.
- W2079432215 hasOpenAccess W2079432215 @default.
- W2079432215 hasPrimaryLocation W20794322151 @default.
- W2079432215 hasRelatedWork W2022996913 @default.
- W2079432215 hasRelatedWork W2025193013 @default.
- W2079432215 hasRelatedWork W2027661934 @default.
- W2079432215 hasRelatedWork W2027956062 @default.
- W2079432215 hasRelatedWork W2032307681 @default.
- W2079432215 hasRelatedWork W2381372014 @default.
- W2079432215 hasRelatedWork W3007507792 @default.
- W2079432215 hasRelatedWork W3020540064 @default.
- W2079432215 hasRelatedWork W4283580548 @default.
- W2079432215 hasRelatedWork W1843679643 @default.
- W2079432215 hasVolume "116" @default.
- W2079432215 isParatext "false" @default.
- W2079432215 isRetracted "false" @default.
- W2079432215 magId "2079432215" @default.
- W2079432215 workType "article" @default.