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- W2079433211 abstract "Solvent-induced frequency shifts in the infrared spectrum of dimethyl sulfoxide (DMSO) and deuterated dimethyl sulfoxide (DMSO-d6) as dilute solutes have been studied in a wide variety of organic solvents. The results obtained show that intermolecular interactions affect vibrations of all the groups in the molecules of the solute, but in different ways and to different extents. The dipole related SO stretching mode in both DMSO and DMSO-d6 appears to be the most sensitive to the molecular environment. Bands corresponding to the νa(CSC) A‘‘ asymmetric stretch in DMSO and the r∥(CD3) A‘ rocking vibration in DMSO-d6 were also chosen as probe modes because they are more clearly observed in all the studied solutions. Complications in the spectrum of DMSO due to the strong overlaps of the bands were avoided by using DMSO-d6. The relative contributions of specific and nonspecific solvation effects were evaluated using a linear solvation energy relationship (LSER). Simple linear equations were obtained for evalua..." @default.
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- W2079433211 title "Solvent-Induced Frequency Shifts in the Infrared Spectrum of Dimethyl Sulfoxide in Organic Solvents" @default.
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- W2079433211 doi "https://doi.org/10.1021/jp951752w" @default.
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