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- W2079436499 abstract "The complex formation of cyclodextrin (CyD, host) with symmetrical p-difluoro-, dichloro-, dibromo-, and diiodobenzenes (guests) has been studied in aqueous medium at 25°C by making use of the volatilization rate of guest molecules from the aqueous into gaseous phase. In the excess of the host, α- and β-CyDs form 1 : 1 and 2 : 1 (host : guest) complexes, while γ-CyD forms 1 : 1 complexes. The association constants, especially for α-and β-CyDs, increased with an increase in the size of the halogen atom. A linear relationship between the logarithm of the 1 : 1 association constant and the total surface area of guest molecule was found for CyD–monohalobenzenes and CyD–p-dihalobenzenes. The van der Waals force seems to be the main factor in stabilizing the associated complexes. The validity of the concept of microscopic binding constant is discussed." @default.
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- W2079436499 date "1991-02-01" @default.
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- W2079436499 title "Association of Symmetrical<i>p</i>-Dihalobenzenes with Cyclodextrins in Aqueous Medium" @default.
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- W2079436499 doi "https://doi.org/10.1246/bcsj.64.480" @default.
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