Matches in SemOpenAlex for { <https://semopenalex.org/work/W2079452636> ?p ?o ?g. }
Showing items 1 to 92 of
92
with 100 items per page.
- W2079452636 endingPage "386" @default.
- W2079452636 startingPage "381" @default.
- W2079452636 abstract "Abstract The lifetimes of the lowest-energy excited state designated 2E, of chromium(III) complexes in fluid solution decrease markedly with increasing temperatures near ambient conditions, but become nearly temperature independent at lower temperatures. The details of the temperature dependence are dependent on the medium and the solvent is implicated as a participant in the quenching process. Perdeuteration of coordinated amine (or ammine) ligands in Cr([14]ane-N4)(CN)2+ai] ([14]aneN4 = 1,4,8,11-tetraazacyclodecane) and Cr(NH3)63+ results in increased lifetimes in all the temperature regimes investigated. This implicates a substantial nuclear reorganizational barrier for the quenching process in fluid solutions. The most likely quenching channel in fluid solutions involves an adiabatic crossing from the excited state potential energy surface of a ground state reaction intermediate." @default.
- W2079452636 created "2016-06-24" @default.
- W2079452636 creator A5057970669 @default.
- W2079452636 creator A5062915614 @default.
- W2079452636 creator A5065669909 @default.
- W2079452636 date "1984-12-01" @default.
- W2079452636 modified "2023-10-16" @default.
- W2079452636 title "Isotopic and steric perturbations of 2E-chromium(III) excited state behavior in fluid solution: Evidence for a solvent mediated, strongly coupled quenching channel" @default.
- W2079452636 cites W1971274408 @default.
- W2079452636 cites W1972170576 @default.
- W2079452636 cites W1981022586 @default.
- W2079452636 cites W1993289989 @default.
- W2079452636 cites W1999297347 @default.
- W2079452636 cites W2011833400 @default.
- W2079452636 cites W2024262348 @default.
- W2079452636 cites W2031517713 @default.
- W2079452636 cites W2056179025 @default.
- W2079452636 cites W2067426469 @default.
- W2079452636 cites W2117487866 @default.
- W2079452636 cites W2338340524 @default.
- W2079452636 cites W2951210501 @default.
- W2079452636 cites W3004815565 @default.
- W2079452636 cites W3138130485 @default.
- W2079452636 cites W4245003988 @default.
- W2079452636 cites W4251025756 @default.
- W2079452636 doi "https://doi.org/10.1016/0009-2614(84)85762-0" @default.
- W2079452636 hasPublicationYear "1984" @default.
- W2079452636 type Work @default.
- W2079452636 sameAs 2079452636 @default.
- W2079452636 citedByCount "14" @default.
- W2079452636 countsByYear W20794526362020 @default.
- W2079452636 crossrefType "journal-article" @default.
- W2079452636 hasAuthorship W2079452636A5057970669 @default.
- W2079452636 hasAuthorship W2079452636A5062915614 @default.
- W2079452636 hasAuthorship W2079452636A5065669909 @default.
- W2079452636 hasConcept C119599485 @default.
- W2079452636 hasConcept C120665830 @default.
- W2079452636 hasConcept C121332964 @default.
- W2079452636 hasConcept C121745418 @default.
- W2079452636 hasConcept C127162648 @default.
- W2079452636 hasConcept C127413603 @default.
- W2079452636 hasConcept C132439834 @default.
- W2079452636 hasConcept C159467904 @default.
- W2079452636 hasConcept C178790620 @default.
- W2079452636 hasConcept C181500209 @default.
- W2079452636 hasConcept C184779094 @default.
- W2079452636 hasConcept C185592680 @default.
- W2079452636 hasConcept C201194858 @default.
- W2079452636 hasConcept C2780471494 @default.
- W2079452636 hasConcept C511782168 @default.
- W2079452636 hasConcept C71240020 @default.
- W2079452636 hasConcept C75473681 @default.
- W2079452636 hasConcept C91881484 @default.
- W2079452636 hasConceptScore W2079452636C119599485 @default.
- W2079452636 hasConceptScore W2079452636C120665830 @default.
- W2079452636 hasConceptScore W2079452636C121332964 @default.
- W2079452636 hasConceptScore W2079452636C121745418 @default.
- W2079452636 hasConceptScore W2079452636C127162648 @default.
- W2079452636 hasConceptScore W2079452636C127413603 @default.
- W2079452636 hasConceptScore W2079452636C132439834 @default.
- W2079452636 hasConceptScore W2079452636C159467904 @default.
- W2079452636 hasConceptScore W2079452636C178790620 @default.
- W2079452636 hasConceptScore W2079452636C181500209 @default.
- W2079452636 hasConceptScore W2079452636C184779094 @default.
- W2079452636 hasConceptScore W2079452636C185592680 @default.
- W2079452636 hasConceptScore W2079452636C201194858 @default.
- W2079452636 hasConceptScore W2079452636C2780471494 @default.
- W2079452636 hasConceptScore W2079452636C511782168 @default.
- W2079452636 hasConceptScore W2079452636C71240020 @default.
- W2079452636 hasConceptScore W2079452636C75473681 @default.
- W2079452636 hasConceptScore W2079452636C91881484 @default.
- W2079452636 hasIssue "4" @default.
- W2079452636 hasLocation W20794526361 @default.
- W2079452636 hasOpenAccess W2079452636 @default.
- W2079452636 hasPrimaryLocation W20794526361 @default.
- W2079452636 hasRelatedWork W1979036730 @default.
- W2079452636 hasRelatedWork W1992767570 @default.
- W2079452636 hasRelatedWork W2001650568 @default.
- W2079452636 hasRelatedWork W2006089966 @default.
- W2079452636 hasRelatedWork W2007439908 @default.
- W2079452636 hasRelatedWork W2047875876 @default.
- W2079452636 hasRelatedWork W2054109876 @default.
- W2079452636 hasRelatedWork W2949366777 @default.
- W2079452636 hasRelatedWork W2997861833 @default.
- W2079452636 hasRelatedWork W3016547980 @default.
- W2079452636 hasVolume "112" @default.
- W2079452636 isParatext "false" @default.
- W2079452636 isRetracted "false" @default.
- W2079452636 magId "2079452636" @default.
- W2079452636 workType "article" @default.