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• W2079461168 endingPage "3218" @default.
• W2079461168 startingPage "3209" @default.
• W2079461168 abstract "The X-ray crystal structure of the complex [Cu2Cl4L2], where L is 2-(2′-pyridyl)quinoxaline, has been determined. The structure consists of dimeric molecules [Cu2Cl4L2], in which copper ions are bridged by two chloride ligands. The geometry at copper can be described as either a distorted square-pyramidal or a distorted trigonalbipyramidal. Magnetic susceptibility and EPR data give evidence for exchange coupling with the best fit to the data of the dimeric expression for a pair of exchange-coupled S = 12 ions yielding g = 2.134, 2J = −10 cm−1 and zJ′ = −2 cm−1. The investigations of the ground-state electronic structure of the complex and its precursor ligand L, along with an orbital interpretation of the magnetic coupling based upon extended Hückel molecular orbital calculations, are also presented." @default.
• W2079461168 created "2016-06-24" @default.
• W2079461168 creator A5030392440 @default.
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• W2079461168 date "1994-12-01" @default.
• W2079461168 modified "2023-10-17" @default.
• W2079461168 title "2-(2′-pyridyl)quinoxaline (L) as a bidentate ligand: crystal structure, magnetic properties and quantum chemical study of [Cu2Cl4L2]" @default.
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• W2079461168 doi "https://doi.org/10.1016/s0277-5387(00)83383-5" @default.
• W2079461168 hasPublicationYear "1994" @default.
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