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- W2079466603 abstract "Vanadium 치환체인 polyoxometalate 1, [Cu(2,2'-bipy)]<TEX>$[Cu(2,2'-bipy)_2]_2[PMo_8V_6O_{42}]{cdot}1.5H_2O$</TEX>을 가지고 있는 inorganicorganic complex의 촉매 활성도를 Biginelli 반응에 적용하여 연구하였다. Dihydropyrimidinones를 one-pot 합성하는 반응에서, <TEX>$H_3PMo_{12}O_{40}$</TEX> 촉매 보다[Cu(2,2'-bipy)]<TEX>$[Cu(2,2'-bipy)_2]_2[PMo_8V_6O_{42}]{cdot}1.5H_2O$</TEX> 촉매가 더 좋은 결과를 나타내었다. The catalytic activity of an inorganic-organic complex with a vanadium-substituted polyoxometalate 1, formulated as [Cu(2,2'-bipy)]<TEX>$[Cu(2,2'-bipy)_2]_2[PMo_8V_6O_{42}]{cdot}1.5H_2O$</TEX> was studied in the Biginelli reactions. The obtained results showed that, in the one-pot synthesis of dihydropyrimidinones, the turnover frequencies (TOF) for the [Cu(2,2'-bipy)]<TEX>$[Cu(2,2'-bipy)_2]_2[PMo_8V_6O_{42}]{cdot}1.5H_2O$</TEX> catalyst were higher than the <TEX>$H_3PMo_{12}O_{40}$</TEX> catalyst." @default.
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- W2079466603 date "2011-08-20" @default.
- W2079466603 modified "2023-10-18" @default.
- W2079466603 title "One-pot Synthesis of Dihydropyrimidinones Using Polyoxometalate Tri-supported Transition Metal Complexes" @default.
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- W2079466603 doi "https://doi.org/10.5012/jkcs.2011.55.4.666" @default.
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