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• W2079467060 abstract "${mathrm{C}}_{59}mathrm{N}$ magnetic fullerenes were formed inside single-wall carbon nanotubes by vacuum annealing functionalized ${mathrm{C}}_{59}mathrm{N}$ molecules encapsulated inside the tubes. A hindered, anisotropic rotation of ${mathrm{C}}_{59}mathrm{N}$ was deduced from the temperature dependence of the electron spin resonance spectra near room temperature. Shortening of the spin-lattice relaxation time ${T}_{1}$ of ${mathrm{C}}_{59}mathrm{N}$ indicates a reversible charge transfer toward the host nanotubes above $ensuremath{sim}350text{ }text{ }mathrm{K}$. Bound ${mathrm{C}}_{59}mathrm{N}mathrm{text{ensuremath{-}}}{mathrm{C}}_{60}$ heterodimers are formed at lower temperatures when ${mathrm{C}}_{60}$ is coencapsulated with the functionalized ${mathrm{C}}_{59}mathrm{N}$. In the 10--300 K range, ${T}_{1}$ of the heterodimer shows a relaxation dominated by the conduction electrons on the nanotubes." @default.
• W2079467060 created "2016-06-24" @default.
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• W2079467060 date "2006-09-25" @default.
• W2079467060 modified "2023-10-17" @default.
• W2079467060 title "Magnetic Fullerenes inside Single-Wall Carbon Nanotubes" @default.
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• W2079467060 doi "https://doi.org/10.1103/physrevlett.97.136801" @default.
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