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- W2079472023 abstract "Enantioselective additions of pyrroles to α,β-unsaturated 2-acyl imidazoles catalyzed by the bis(oxazolinyl)pyridine−scandium(III) triflate complex (1) have been accomplished. The α,β-unsaturated 2-acyl imidazoles were synthesized in high yields through Wittig olefination. A short, enantioselective synthesis of the alkaloid (+)-heliotridane has been accomplished utilizing this methodology and a 2-acyl imidazole cleavage and cyclization. This methodology was then extended to the one-pot asymmetric synthesis of 2-substituted indoles." @default.
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- W2079472023 date "2006-05-01" @default.
- W2079472023 modified "2023-10-16" @default.
- W2079472023 title "Catalytic Enantioselective Pyrrole Alkylations of α,β-Unsaturated 2-Acyl Imidazoles" @default.
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- W2079472023 doi "https://doi.org/10.1021/ol060576e" @default.
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