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- W2079482638 abstract "Abstract Molybdenum availability in soils may be altered with P additions. Sorption-desorption of Mo as a function of added P was studied in two soils, a Dalhousie (Humic-gleysol) clay and a St. Bernard (Eutric-cambisol) loam. The soil samples were shaken with solutions containing varying amounts of phosphates and molybdates in 0.03 M KClO4. The first equilibration measured P sorption, the second Mo sorption and P desorption, and the third Mo desorption and further P desorption. Each equilibration was carried out for 72 h. Initial pH of the solutions was held at 6.0. Sorbed P reduced Mo sorption, especially at high P addition levels. Of the Freundlich, Langmuir, Gunary and Temkin isotherms, the experimental data fitted the Temkin isotherm best. The presence of P reduced the intercept values of the Temkin equation, indicating a reduced affinity of surfaces for Mo. In the presence of various amounts of sorbed P, Mo sorption was described best by Gunary isotherms that included a P term (itr2 > 0.93, P" @default.
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- W2079482638 date "1991-05-01" @default.
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- W2079482638 title "Molybdate sorption-desorption in soils treated with phosphate" @default.
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- W2079482638 doi "https://doi.org/10.1016/0016-7061(91)90051-t" @default.
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