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- W2079484855 abstract "Chiral dithioether ligands have been tested in the model Pd-catalysed allylic alkylation reaction of (±)-3-acetoxy-1,3-diphenyl-1-propene with dimethyl malonate, giving high enantioselectivity (up to 81% e.e.) for the first time in this type of system. Pd(II)-allylic intermediates, [Pd(η3-1,3-Ph2-C3H3)(dithioether)]PF6 were prepared and characterised both in solution by NMR spectroscopy and solid state. The X-ray structure for [Pd(η3-1,3-Ph2-C3H3)(L)]PF6 (L=(R,R)-7,8-O-isopropylidene-1,5-dithia-cyclononane) was determined." @default.
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- W2079484855 date "2001-06-01" @default.
- W2079484855 modified "2023-10-16" @default.
- W2079484855 title "Chiral S,S-donor ligands in palladium-catalysed allylic alkylation" @default.
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- W2079484855 doi "https://doi.org/10.1016/s0957-4166(01)00260-9" @default.
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