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- W2079485736 abstract "The neutral products resulting from the degradation of aromatic nitrocompounds, following interaction with argon metastables (presumably by Penning ionization), have been studied inside a gas chromatographic system. The simplest but typical example, nitrobenzene, yields benzene and phenol. Product ratios sometimes resemble results of mass spectrometry more than they do data obtained by pyrolysis. The ease of elimination of substituents from monohalogenated nitrobenzenes follows the order I > NO 2 > Br > Cl. Ratios of the products resulting from loss of NO (rearrangement) versus loss of NO 2 have been measured for a variety of compounds. The leaving NO 2 group can be replaced by I if the system is doped with iodine vapour. Reduction of the nitro group and ring closures are observed with some of the more complex substrates, similar to results known from discharge chemistry." @default.
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- W2079485736 date "1981-05-15" @default.
- W2079485736 modified "2023-09-24" @default.
- W2079485736 title "Products from interaction of aromatic nitrocompounds with argon metastables inside a gas chromatograph" @default.
- W2079485736 doi "https://doi.org/10.1139/v81-211" @default.
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