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• W2079485887 abstract "The electron density of the $ensuremath{alpha}$ form of boron has been obtained by multipole refinement against high-resolution, single-crystal x-ray diffraction data measured on a high-quality single crystal at a temperature of 100 K. Topological properties of this density have been used to show that all chemical bonds between B${}_{12}$ clusters in $ensuremath{alpha}$-B${}_{12}$ are formed due to one orbital on each boron atom that is oriented perpendicular to the surface of the cluster. It is shown that the same orbital order on B${}_{12}$ clusters persists in both $ensuremath{alpha}$-B${}_{12}$ and $ensuremath{gamma}$-B${}_{28}$ polymorphs and in several dodecaboranes, despite the fact that in every case the B${}_{12}$ clusters participate in entirely different kinds of exocluster bonds. It is likely that the same orbital order of B${}_{12}$ clusters can explain bonding in other boron polymorphs and boron-rich solids." @default.
• W2079485887 created "2016-06-24" @default.
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• W2079485887 date "2013-07-29" @default.
• W2079485887 modified "2023-10-16" @default.
• W2079485887 title "Experimental evidence of orbital order in<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mi>α</mml:mi></mml:math>-B<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:msub><mml:mrow /><mml:mn>12</mml:mn></mml:msub></mml:math>and<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mi>γ</mml:mi></mml:math>-B<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:msub><mml:mrow /><mml:mn>28</…" @default.
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• W2079485887 doi "https://doi.org/10.1103/physrevb.88.024118" @default.
• W2079485887 hasPublicationYear "2013" @default.
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