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- W2079495842 abstract "Abstract A 1:2:2:6 molar ratio of Cd(NO3)2 · 4H2O, Cu(NO3)2 · 3H2O, tris(2-aminoethylamine) (tren) and NH4NCS in aqueous solution at room temperature affords trinuclear complex of the type [Cu2Cd(tren)2(NCS)6] (1). The complex has been characterised using microanalytical, spectroscopic and magnetic results. X-ray diffraction measurements have been made to define the coordination sphere and long-range structure. 1 consists of two pentacoordinated copper(II) occupied by tren N atoms and one bridging SCN− N atom of the central trans-[Cd(NCS)4(SCN)2]4− molecular ion which bridges by the 1,3-thiocyanate. Each of these trinuclear units are engaged in intra as well as intermolecular N–H⋯S hydrogen bonding. Variable-temperature magnetic study shows no significant magnetic interactions among the metal ions." @default.
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- W2079495842 date "2006-04-01" @default.
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- W2079495842 title "Synthesis, structure and properties of a trinuclear compound [Cu2Cd(tren)2(NCS)6]: Example of dynamic molecular ion, [Cd(NCS)6−n(SCN)n]4−(n=0–6)" @default.
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- W2079495842 doi "https://doi.org/10.1016/j.poly.2005.10.010" @default.
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