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- W2079496776 abstract "Abstract Iron oxide is used as a support for molybdenum oxide to investigate the activity of Fe-Mo oxide catalyst for methanol oxidation. In less than 6 nm −2 of molybdenum concentration and less than ca. 70% coverage, MoO 3 is supported as a monolayer on Fe 2 O 3 . In this range of molybdenum concentration, the turn-over frequency increased linearly with the number of molybdenum atoms exposed, and finally attained a constant value. It was concluded that the molybdena monolayer was active, and the two neighboring molybdenum sites played the role of active sites, simultaneously; one for adsorption of methanol and the other for abstraction of hydrogen. The structure of the molybdena monolayer seems to be similar to that of iron-defective Fe 2 (MoO 4 ) 3 with MoO 3 ." @default.
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- W2079496776 date "1993-03-01" @default.
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- W2079496776 title "Methanol oxidation on a molybdena monolayer supported on iron oxide" @default.
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- W2079496776 doi "https://doi.org/10.1016/0926-860x(90)80004-x" @default.
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