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- W2079504208 abstract "Herein we report FTIR in situ adsorption of molecular hydrogen, carbon monoxide, water, methanol, pyridine and 2,4,6-trimethylpyridine (collidine) on nanosheet H-ZSM-5 which was recently studied in the methanol to hydrocarbons (MTH) reaction. The nature of the hydroxyl groups and surface species are described in detail. The IR spectrum of nanosheet H-ZSM-5 is dominated by silanols, which saturate the external surfaces. The acidity of Si(OH)Al is comparable to that observed in the case of standard microcrystalline H-ZSM-5. The study of the external surface allows the recognition of Si(OH)Al species located at the channel entrance, which are mostly all accessible to hindered molecules such as collidine." @default.
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- W2079504208 date "2013-01-01" @default.
- W2079504208 modified "2023-09-29" @default.
- W2079504208 title "Probing the surface of nanosheet H-ZSM-5 with FTIR spectroscopy" @default.
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- W2079504208 doi "https://doi.org/10.1039/c3cp51280k" @default.
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