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• W2079540982 abstract "The rate coefficients for the reactions of C2H and C2D with O2 have been measured in the temperature range 295 K ⩽ T ⩽ 700 K. Both reactions show a slightly negative temperature dependence in this temperature range, with kC2H+O2 = (3.15 ± 0.04) × 10−11 (T/295 K)−(0.16 ± 0.02) cm3 molecule−1 s−1. The kinetic isotope effect is kC2HkC2D = 1.04 ± 0.03 and is constant with temperature to within experimental error. The temperature dependence and the C2H + O2 kinetic isotope effect are consistent with a capture-limited metathesis reaction, and suggest that formation of the initial HCCOO adduct is rate-limiting." @default.
• W2079540982 created "2016-06-24" @default.
• W2079540982 creator A5015716392 @default.
• W2079540982 creator A5062457472 @default.
• W2079540982 date "1997-05-01" @default.
• W2079540982 modified "2023-09-25" @default.
• W2079540982 title "Temperature dependence of the reaction C2H (C2D) + O2 between 295 and 700 K" @default.
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• W2079540982 doi "https://doi.org/10.1016/s0009-2614(97)00396-5" @default.
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