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- W2079543729 abstract "The intramolecularly stabilized organogallium compounds ClGa(CH2CH2CH2)2NCH3 (1), RGa(CH2CH2CH2)2NCH3 (R Pr, iPr, Bu, tBu, Ph, CH2SiMe3, (CH2)3NMe2, (CH2)3NEt2, CH2CHMeCH2NMe2, C6H4CH2NMe2, H, (4–14)) and the indium analogs ClIn(CH2CH2CH2)2NCH3 (16) and HIn(CH2CH2CH2)2NCH3 (17) have been synthesized from GaCl3 or InCl3 and bis[(3-chloromagnesio)propyl]methylamine and subsequent reaction with the appropriate Grignard reagents RMgX, with RLi or lithium hydride, respectively. HGa(CH2CH2CH2)2NCH3 (14) inserts CO2 yielding HO2CGa(CH2CH2CH2)2NCH3 (15). The 1H-, 13C-NMR and mass spectra of the new compounds as well as the X-ray crystal structure analyses of 1, 12, 14 and 15 are reported and discussed. Intramolekular stabilisierte Organogalliumverbindungen ClGa(CH2CH2CH2)2NCH3 (1), RGa(CH2CH2CH2)2NCH3 (R Pr, iPr, Bu, tBu, Ph, CH2SiMe3, (CH2)3NMe2, (CH2)3NEt2, CH2CHMeCH2NMe2, C6H4CH2NMe2, H, (4–14)) und die Indium Analoga ClIn(CH2CH2CH2)2NCH3 (16) und HIn(CH2CH2CH2)2NCH3 (17) wurden aus GaCl3 bzw. InCl3 und Bis[(3-chloromagnesio)propyl]methylamin und nachfolgende Reaktion mit entsprechenden Grignard-Reagentien RMgX, mit Lithiumorganylen oder Lithiumhydrid synthetisiert. HGa(CH2CH2CH2)2NCH3 (14) reagiert mit CO2 unter Insertion in die GaH-Bindung und Bildung von HO2CGa(CH2CH2CH2)2NCH3 (15). Die 1H-, 13C-NMR und Massenspektren der neuen Verbindungen, sowie die Ergebnisse der Röntgenstrukturanalysen von 1, 12, 14 und 15 werden diskutiert." @default.
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- W2079543729 date "1994-06-01" @default.
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- W2079543729 title "Intramolekular stabilisierte gallium- und indiumorganyle: Synthese und röntgenstrukturanalyse repräsentativer 5-Methyl-1-galla(inda)-5-azacyclooktane" @default.
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- W2079543729 doi "https://doi.org/10.1016/0022-328x(94)80189-4" @default.
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