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- W2079553376 abstract "Lanthanide(III) salts were found to act as templates for the cyclic condensation of organic dicarbonyl compounds with primary diamines to yield complexes of macrocyclic Schiff-base ligands in moderate to good yield. Three types of macrocyclic lanthanide(III) complexes were obtained: (i) mononuclear complexes of an 18-membered sexidentate N3O3 macrocycle derived from the reaction of 2,6-diacetylpyridine with 1,5-bis(2-aminophenoxy)-3-oxapentane; (ii) mononuclear complexes of 15-membered pentadentate N3O2 macrocycles derived from the reactions of 2,6-diacetyl- or 2,6-diformyl-pyridine with 1,2-bis(2-aminophenoxy)ethane. The complexes were characterised by elemental analyses, molar conductivity, mass, IR and 1H NMR spectroscopy and thermogravimetric and magnetic measurements." @default.
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- W2079553376 date "1996-01-01" @default.
- W2079553376 modified "2023-10-17" @default.
- W2079553376 title "Complexes of lanthanide(<scp>III</scp>) ions with macrocyclic ligands containing pyridine head units" @default.
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- W2079553376 doi "https://doi.org/10.1039/dt9960001493" @default.
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