Matches in SemOpenAlex for { <https://semopenalex.org/work/W2079554294> ?p ?o ?g. }
Showing items 1 to 85 of
85
with 100 items per page.
- W2079554294 endingPage "1655" @default.
- W2079554294 startingPage "1654" @default.
- W2079554294 abstract "Catalytic asymmetric cross-coupling reactions between aldehydes and N-acylimines have been discovered that employ thiazolylalanine derivatives as catalysts. Alkylation of the thiazolyl moiety, followed by in situ generation of the derived thiazolium ylide using a tertiary amine base, leads to the active catalyst. α-Amidoketone products are isolated in up to 90% yield with up to 87% enantiomeric excess (>98% ee after a single recrystallization). The use of a hindered base to suppress product racemization was stimulated by a mechanistic study that revealed an isotope effect on the racemization rate of the product." @default.
- W2079554294 created "2016-06-24" @default.
- W2079554294 creator A5023635918 @default.
- W2079554294 creator A5050993641 @default.
- W2079554294 creator A5073335566 @default.
- W2079554294 creator A5084218301 @default.
- W2079554294 date "2005-01-22" @default.
- W2079554294 modified "2023-10-02" @default.
- W2079554294 title "Thiazolylalanine-Derived Catalysts for Enantioselective Intermolecular Aldehyde−Imine Cross-Couplings" @default.
- W2079554294 cites W2006009683 @default.
- W2079554294 cites W2022624426 @default.
- W2079554294 cites W2145966973 @default.
- W2079554294 doi "https://doi.org/10.1021/ja042650z" @default.
- W2079554294 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15700996" @default.
- W2079554294 hasPublicationYear "2005" @default.
- W2079554294 type Work @default.
- W2079554294 sameAs 2079554294 @default.
- W2079554294 citedByCount "168" @default.
- W2079554294 countsByYear W20795542942012 @default.
- W2079554294 countsByYear W20795542942013 @default.
- W2079554294 countsByYear W20795542942014 @default.
- W2079554294 countsByYear W20795542942015 @default.
- W2079554294 countsByYear W20795542942016 @default.
- W2079554294 countsByYear W20795542942017 @default.
- W2079554294 countsByYear W20795542942018 @default.
- W2079554294 countsByYear W20795542942019 @default.
- W2079554294 countsByYear W20795542942020 @default.
- W2079554294 countsByYear W20795542942021 @default.
- W2079554294 countsByYear W20795542942022 @default.
- W2079554294 countsByYear W20795542942023 @default.
- W2079554294 crossrefType "journal-article" @default.
- W2079554294 hasAuthorship W2079554294A5023635918 @default.
- W2079554294 hasAuthorship W2079554294A5050993641 @default.
- W2079554294 hasAuthorship W2079554294A5073335566 @default.
- W2079554294 hasAuthorship W2079554294A5084218301 @default.
- W2079554294 hasConcept C131779359 @default.
- W2079554294 hasConcept C146686406 @default.
- W2079554294 hasConcept C155647269 @default.
- W2079554294 hasConcept C161790260 @default.
- W2079554294 hasConcept C164361826 @default.
- W2079554294 hasConcept C178790620 @default.
- W2079554294 hasConcept C185592680 @default.
- W2079554294 hasConcept C2776568683 @default.
- W2079554294 hasConcept C2776573223 @default.
- W2079554294 hasConcept C2779167645 @default.
- W2079554294 hasConcept C2779825165 @default.
- W2079554294 hasConcept C3141732 @default.
- W2079554294 hasConcept C486523 @default.
- W2079554294 hasConcept C60002323 @default.
- W2079554294 hasConceptScore W2079554294C131779359 @default.
- W2079554294 hasConceptScore W2079554294C146686406 @default.
- W2079554294 hasConceptScore W2079554294C155647269 @default.
- W2079554294 hasConceptScore W2079554294C161790260 @default.
- W2079554294 hasConceptScore W2079554294C164361826 @default.
- W2079554294 hasConceptScore W2079554294C178790620 @default.
- W2079554294 hasConceptScore W2079554294C185592680 @default.
- W2079554294 hasConceptScore W2079554294C2776568683 @default.
- W2079554294 hasConceptScore W2079554294C2776573223 @default.
- W2079554294 hasConceptScore W2079554294C2779167645 @default.
- W2079554294 hasConceptScore W2079554294C2779825165 @default.
- W2079554294 hasConceptScore W2079554294C3141732 @default.
- W2079554294 hasConceptScore W2079554294C486523 @default.
- W2079554294 hasConceptScore W2079554294C60002323 @default.
- W2079554294 hasIssue "6" @default.
- W2079554294 hasLocation W20795542941 @default.
- W2079554294 hasLocation W20795542942 @default.
- W2079554294 hasOpenAccess W2079554294 @default.
- W2079554294 hasPrimaryLocation W20795542941 @default.
- W2079554294 hasRelatedWork W1977545362 @default.
- W2079554294 hasRelatedWork W2047888616 @default.
- W2079554294 hasRelatedWork W2079554294 @default.
- W2079554294 hasRelatedWork W2146568308 @default.
- W2079554294 hasRelatedWork W2725052561 @default.
- W2079554294 hasRelatedWork W2953124286 @default.
- W2079554294 hasRelatedWork W2953270462 @default.
- W2079554294 hasRelatedWork W2979972960 @default.
- W2079554294 hasRelatedWork W4231225687 @default.
- W2079554294 hasRelatedWork W4282831597 @default.
- W2079554294 hasVolume "127" @default.
- W2079554294 isParatext "false" @default.
- W2079554294 isRetracted "false" @default.
- W2079554294 magId "2079554294" @default.
- W2079554294 workType "article" @default.