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- W2079559354 abstract "In order to characterize the reaction mechanism of lithium-ion cells during charge and discharge, two experimental methods, calorimetry and staircase voltage step coulometry (SVSC), are examined. As a result of calorimetry during charge and discharge, the influence of previous treatment applied to the cell is observed in the heat generation behavior. SVSC gives kinetic information of the rate-determining step in the cell reaction. It is found that there is a slow-rate reaction besides the main cell reaction during charge and discharge. It is suggested that the irreversibility of the slow-rate reaction causes the voltage hysteresis between charge and discharge. The cell reaction mechanism is discussed, mainly focusing the reaction at the hard carbon anode used in the test cell." @default.
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- W2079559354 date "1999-09-01" @default.
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- W2079559354 title "Characterization of reaction in lithium-ion cells by calorimetry and staircase voltage step coulometry" @default.
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- W2079559354 doi "https://doi.org/10.1016/s0378-7753(99)00134-2" @default.
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