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- W2079570900 abstract "Die Thermolyse der 1,2-Dioxetane 1–4 wird bei linear steigender Temperatur anhand der Chemilumineszenz verfolgt. Die erhaltenen Kurven für die Emissionsintensität I als Funktion der Temperatur T werden mit aus der Differential-Thermo-Analyse bekannten Abhängigkeiten verglichen und nach ähnlichen Verfahren ausgewertet. Durch diese Arbeitsweise wurde festgestellt, daß unter den angewandten Bedingungen die Quantenausbeute der Chemilumineszenz ø⋆ bei 1–4 keine Funktion der Temperatur ist. Application of Non-Isothermal Kinetics to Chemiluminescent Systems. Thermolysis of 1,2-Dioxetanes The thermolysis of the 1,2-dioxetanes 1–4 is monitored by their chemiluminescence emission under the condition of a linear temperature-rise. The dependence of emission intensity I on temperature T is compared with known functions in differential-thermal-analysis and is evaluated by similar methods. With this technique it was shown that in the case of the dioxetanes 1–4 the quantum yield of chemiluminescence ø⋆ is not a function of temperature under the applied conditions." @default.
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- W2079570900 date "1976-08-01" @default.
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- W2079570900 title "Anwendung nicht‐isothermer Kinetik auf chemilumineszente Systeme. Thermolyse von 1,2‐Dioxetanen" @default.
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- W2079570900 doi "https://doi.org/10.1002/cber.19761090818" @default.
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