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- W2079572733 abstract "The kinetics of growth of calcium phosphate on hydroxyapatite seed crystals was studied at 25 °C and at constant physiological pH in stable supersaturated solutions of calcium phosphate containing various concentrations of magnesium ion. The pH was maintained constant by means of the pH-stat controlled addition of base and the growth was followed by analyzing the solutions for calcium, phosphate and magnesium. Grown material was characterized chemically, by subsequent dissolution kinetic experiments, by infrared spectroscopy and by specific surface area measurement. Magnesium ion reduces the overall rate of crystallization by stabilizing the precursor formed initially in the growth runs. Whereas the stoichiometry of the first formed surface phase corresponds to that of octacalcium phosphate (OCP) in the absenȩ of magnesium, lower molar Ca:P ratios, possibly a mixture of dicalcium phosphate dihydrate (DCPD) and OCP, are indicated in its presence." @default.
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- W2079572733 date "1975-12-01" @default.
- W2079572733 modified "2023-10-17" @default.
- W2079572733 title "Growth of calcium phosphates on hydroxyapatite crystals: The effect of magnesium" @default.
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- W2079572733 doi "https://doi.org/10.1016/0003-9969(75)90057-6" @default.
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