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• W2079580083 abstract "The resonance Raman spectra of a mixed-valence copper dimer [Cu2(L)]3+ encapsulated by the ligand L = N(CH2CH2N(H)CH2CH2N(H)CH2CH2)3N are reported. Copper isotope data (63/65Cu) of solution spectra of [Cu2(L)]3+ allow identification of vibrational bands at 289 and 172 cm-1 as predominately Cu−Cu stretching and Cu−Cu−Neq bending modes. The results indicate that the Cu−Cu bond is sufficiently weak that ligand conformations, influenced by hydrogen bonding, can give rise to distortional isomers of the Cu−Cu bond." @default.
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• W2079580083 date "1999-05-01" @default.
• W2079580083 modified "2023-10-14" @default.
• W2079580083 title "Distortional Isomers of a Mixed-Valence Binuclear Cu Complex" @default.
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• W2079580083 doi "https://doi.org/10.1021/ic981415c" @default.
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