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- W2079582561 abstract "The common FGHI-ring part (2) of ciguatoxins has been synthesized from the F- and I-ring parts (6 and 5, respectively). The Nozaki–Hiyama–Kishi coupling of 6 with 5 followed by regio- and stereoselective epoxidation at C29 and C30 afforded an epoxide (4), which was transformed into a tricyclic compound (3) corresponding to the F-HI-ring part by 6-exo-epoxide opening and the subsequent inversion of the C29 stereocenter. Reductive cyclization of 3 forming the C31–O26 bond of the G-ring successfully produced 2." @default.
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- W2079582561 date "2006-01-01" @default.
- W2079582561 modified "2023-10-09" @default.
- W2079582561 title "Synthesis of the common FGHI-ring part of ciguatoxins" @default.
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- W2079582561 doi "https://doi.org/10.1016/j.tetlet.2005.11.085" @default.
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