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• W2079589321 abstract "A series of 11 simple phylloquinone derivatives, each lacking the extended phytyl side chain but featuring H-bond donor amides at one or both peri positions, were prepared and some salient physical properties were measured. A correlation between both IR frequency and NMR peak position, as indicators of internal H-bond strength, and the quinone half-wave reduction potential, was observed. These data are consistent with the prevailing hypothesis that quinone carbonyl H-bonding in general, and stronger H-bonds in particular, favorably bias the endogenous quinone’s electrochemical potential toward easier reduction." @default.
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• W2079589321 date "2007-09-01" @default.
• W2079589321 modified "2023-10-17" @default.
• W2079589321 title "A relationship between amide hydrogen bond strength and quinone reduction potential: Implications for photosystem I and bacterial reaction center quinone function" @default.
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• W2079589321 doi "https://doi.org/10.1016/j.bmcl.2007.06.041" @default.
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