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- W2079595684 abstract "Addition of excess lithium salts of (−)-menthol or (−)-borneol to 2,3-dicarbomethoxynorbornadiene 1 affords the transesterification–addition products 4 and 5. The thiols derived from the same monoterpenes give only the addition products to the activated double bond, 6 and 7. In all cases, the addition reaction is totally exo-selective with respect to the norbornadiene moiety and moderately selective in discriminating the si- and re-face of the double bond. Both diastereomeric products are formed as a mixture of endo–exo epimers at C3. The major addition product of (−)-menthol to 1 is crystalline, of known absolute configuration, and has potential as a precursor of chiral ligands." @default.
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- W2079595684 date "2000-07-01" @default.
- W2079595684 modified "2023-10-03" @default.
- W2079595684 title "Diastereoselective addition of monoterpenic alcoholates and thiolates to 2,3-dicarbomethoxynorbornadiene" @default.
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- W2079595684 doi "https://doi.org/10.1016/s0957-4166(00)00231-7" @default.
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