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• W2079596916 endingPage "17906" @default.
• W2079596916 startingPage "17899" @default.
• W2079596916 abstract "Abstract We report on the first homoleptic tetrakis(silyl) complexes of zerovalent Group 10 metals. The compounds [MLi 4 {Si(3,5‐Me 2 pz) 3 } 4 ] (M=Pd and Pt; 3,5‐Me 2 pz=3,5‐dimethylpyrazolyl) exhibit very appealing metal‐centred heterocubane structures with the central d 10 metal atoms surrounded by four silicon and four lithium atoms. Both compounds were characterised in detail, including X‐ray crystal‐structure analysis and 2D NMR spectroscopic methods such as 7 Li, 29 Si and 7 Li, 195 Pt HMQC. Cyclic voltammetry studies, in combination with density functional theory (DFT) calculations, revealed that the corresponding mononuclear cationic d 9 ‐M I and dicationic d 8 ‐M II complexes are accessible by stepwise one‐electron oxidation of the title compounds. Electron paramagnetic resonance (EPR) investigations provided evidence for the existence of the corresponding paramagnetic palladium(I) and platinum(I) complexes." @default.
• W2079596916 created "2016-06-24" @default.
• W2079596916 creator A5003003390 @default.
• W2079596916 creator A5013590724 @default.
• W2079596916 creator A5018654878 @default.
• W2079596916 creator A5062197883 @default.
• W2079596916 date "2013-11-21" @default.
• W2079596916 modified "2023-10-18" @default.
• W2079596916 title "Homoleptic Tetrakis(silyl) Complexes of Pd⁰and Pt⁰Featuring Metal-Centred Heterocubane Structures: Evidence for the Existence of the Corresponding Mononuclear Pd^Iand Pt^IComplexes" @default.
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