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• W2079600548 abstract "The performance of calix[2]furano[2]pyrrole and related compounds used as neutral carriers for silver selective polymeric membrane electrode was investigated. The silver ion-selective electrode based on calix[2]furano[2]pyrroles gave a good Nernstian response of 57.1 mV per decade for silver ion in the activity range 1×10−6 to 1×10−2 M. The present silver ion-selective electrode displayed very good selectivity for Ag+ ion against alkali and alkaline earth metal ions, NH4+, and H+. In particular, the present Ag+-selective electrode exhibited very low responses towards Hg2+ and Pb2+ ions. The potentiometric selectivity coefficients of the silver ion-selective electrode exhibited a strong dependence on the solution pH. In particular, the response of the electrode to the Hg2+ activity was greatly diminished at pH 2.5 compared to that at pH 5.0. Overall, the performance of the present silver ion-selective electrode based on the ionophore, calix[2]furano[2]pyrrole, is very comparable to that of the electrode prepared with the commercially available neutral carrier in terms of slope, linear range, and detection limits." @default.
• W2079600548 created "2016-06-24" @default.
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• W2079600548 date "2002-02-01" @default.
• W2079600548 modified "2023-09-23" @default.
• W2079600548 title "Calix[2]furano[2]pyrrole and related compounds as the neutral carrier in silver ion-selective electrode" @default.
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• W2079600548 doi "https://doi.org/10.1016/s0003-2670(01)01493-3" @default.
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