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• W2079609474 abstract "A general method for high-resolution ion excitation, ejection, and isolation is developed from linear response theory for resonant dipolar excitation of the axial z-oscillatory motion of ions in a quadrupole (Paul) ion trap operated in rf-only mode. For a spatially uniform dipolar excitation field, the ion z-oscillation amplitude is directly proportional to the amplitude of the Fourier component of the excitation at the axial oscillation frequency of that ion. Thus, one may specify an arbitrary z-motion frequency-domain spectrum by applying a time-domain stored waveform obtained from the inverse Fourier transform of the corresponding frequency-domain excitation spectrum. The stored waveform inverse Fourier transform (SWIFT) waveform may be tailored for selective ejection or excitation of ions of arbitrary mass-to-charge ratio ranges. The method includes all other possible excitation/ejection waveforms (e.g., single frequency, frequency sweep) as special cases. The effect of collisional damping during excitation is included in the analytical solution of the ion response." @default.
• W2079609474 created "2016-06-24" @default.
• W2079609474 creator A5054032458 @default.
• W2079609474 creator A5091203766 @default.
• W2079609474 date "1993-05-01" @default.
• W2079609474 modified "2023-10-18" @default.
• W2079609474 title "Stored waveform inverse Fourier transform axial excitation/ejection for quadrupole ion trap mass spectrometry" @default.
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• W2079609474 doi "https://doi.org/10.1021/ac00057a029" @default.
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