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- W2079619334 abstract "Knudsen-effusion mass spectrometry has been used to study the vaporization behaviour of SrB 2 O 4 (s or l) in the temperature range 1310 to 1442 K. Vapours of Sr(g), SrBO 2 (g), BO(g), B 2 O 2 (g), and B 2 O 3 (g) have been identified. On the basis of their partial pressures, the molar enthalpies of formation and dissociation for SrBO 2 (g) have been determined to be Δ f H m o (SrBO 2 , g, 298.15 K) = −(636±19) kJ·mol −1 and { Δ f H m o (Sr, g, 298.15 K) + Δ f H m o (BO 2 , g, 298.15 K) − Δ f H m o (SrBO 2 , g, 298.15 K)} = (516±17) kJ·mol −1 , respectively, and the molar enthalpies of formation for SrB 2 O 4 (s) from elements and from constituent oxides to be Δ f H m o (SrBO 2 , s, 298.15 K) = −(2017±29) kJ·mol −1 and { Δ f H m o (SrB 2 O 4 , s, 298.15 K) − Δ f H m o (SrO, s, 298.15 K) − Δ f H m o (B 2 O 3 , s, 298.15 K)} = −(153±29) kJ·mol −1 , respectively." @default.
- W2079619334 created "2016-06-24" @default.
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- W2079619334 date "1988-10-01" @default.
- W2079619334 modified "2023-10-06" @default.
- W2079619334 title "Thermochemical properties of SrBO2(g) and SrB2O4(s)" @default.
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- W2079619334 doi "https://doi.org/10.1016/0021-9614(88)90098-5" @default.
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