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• W2079632339 abstract "The molybdenum atom in FeMoco is imperative to the high activity of the enzyme and has been proposed to be Mo(<sc>iv</sc>). We demonstrate that only Mo(<sc>iii</sc>) fits Mo HERFD XAS data, the first example of Mo(<sc>iii</sc>) in biology. Theoretical calculations further reveal an unusual spin-coupled Mo(<sc>iii</sc>)." @default.
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• W2079632339 date "2014-01-01" @default.
• W2079632339 modified "2023-10-13" @default.
• W2079632339 title "Identification of a spin-coupled Mo(<scp>iii</scp>) in the nitrogenase iron–molybdenum cofactor" @default.
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• W2079632339 doi "https://doi.org/10.1039/c4sc00337c" @default.
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