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- W2079639087 abstract "meso- and racemic-1,2-diethyl-1,2-dimethyldiphenyldisilane (2a) and (2b) were synthesized respectively by hydrogenation of meso- and racemic-1,2-diethynyl-1,2-dimethyldiphenyldisilane in the presence of a IrCl(CO)(PPh3)2 catalyst. Irradiation of 2a with a low-pressure mercury lamp in the presence of isobutene in hexane proceeded with high diastereospecificity to give (R,S)- and (S,R)-2-(isobutylethylmethylsilyl)-1-(ethylmethylphenylsilyl)benzene in 77% yield. Similar irradiation of 2b with isobutene produced (R,R)- and (S,S)-isomer. The photolysis of 2a and 2b in the presence of 1,1-diphenylethylene also proceeded diastereospecifically to give the respective adducts. With 2,3-dimethylbutadiene, 2a and 2b produced the corresponding adducts, whose spectrometric analysis showed the presence of two diastereomers. Results on theoretical studies which were carried out using PhSiH2SiH3 as a model have also been reported." @default.
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- W2079639087 date "1996-01-01" @default.
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- W2079639087 title "Silicon−Carbon Unsaturated Compounds. 57. Photolysis of <i>meso-</i> and <i>racemic-</i>1,2-Diethyl-1,2-dimethyldiphenyldisilane, Direct Evidence for a Concerted 1,3-Silyl Shift to <i>ortho</i>-Carbon in the Phenyl Ring" @default.
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- W2079639087 doi "https://doi.org/10.1021/ja960458u" @default.
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