FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2079641189> ?p ?o ?g. }

• W2079641189 endingPage "2538" @default.
• W2079641189 startingPage "2525" @default.
• W2079641189 abstract "The concept of the nanoreactor valuably contributes to catalytic applications of supramolecular chemistry. Therewith molecular engineering may lead to organic transformations that minimize the amount of metal catalyst to reach the efficiency of enzymatic catalysis. The design of the dendritic nanoreactor proposed here involves hydrophilic triethylene glycol (TEG) termini for solubilization in water and water/ethanol mixed solvents combined with a hydrophobic dendritic interior containing 1,2,3-triazole ligands that provide smooth stabilization of very small (1 to 2 nm) palladium nanoparticles (PdNPs). The PdNPs stabilized in such nanoreactors are extraordinarily active in water/ethanol (1/1) for the catalysis of various carbon-carbon coupling reactions (Suzuki–Miyaura, Heck and Sonogashira) of aryl halides down to sub-ppm levels for the Suzuki–Miyaura coupling of aryl iodides and aryl bromides. The reduction of 4-nitrophenol to 4-aminophenol in water also gives very impressive results. The difference of reactivity between the two distinct dendrimers with, respectively, 27 (G0) and 81 (G1) TEG termini is assigned to the difference of PdNP core size, the smaller G0 PdNP core being more reactive than the G1 PdNP core (1.4 vs. 2.7 nm), which is also in agreement with the leaching mechanism." @default.
• W2079641189 created "2016-06-24" @default.
• W2079641189 creator A5026455010 @default.
• W2079641189 creator A5071668591 @default.
• W2079641189 creator A5075036279 @default.
• W2079641189 date "2014-06-20" @default.
• W2079641189 modified "2023-10-15" @default.
• W2079641189 title "“Click” Dendrimer-Stabilized Palladium Nanoparticles as a Green Catalyst Down to Parts per Million for Efficient CC Cross-Coupling Reactions and Reduction of 4-Nitrophenol" @default.
• W2079641189 cites W1964293944 @default.
• W2079641189 cites W1964974884 @default.
• W2079641189 cites W1965186270 @default.
• W2079641189 cites W1965539465 @default.
• W2079641189 cites W1968641485 @default.
• W2079641189 cites W1970381834 @default.
• W2079641189 cites W1971532176 @default.
• W2079641189 cites W1974166089 @default.
• W2079641189 cites W1977404484 @default.
• W2079641189 cites W1977886727 @default.
• W2079641189 cites W1978267907 @default.
• W2079641189 cites W1978890358 @default.
• W2079641189 cites W1979694566 @default.
• W2079641189 cites W1981530531 @default.
• W2079641189 cites W1981599309 @default.
• W2079641189 cites W1981754097 @default.
• W2079641189 cites W1983504610 @default.
• W2079641189 cites W1984909498 @default.
• W2079641189 cites W1985042246 @default.
• W2079641189 cites W1989172956 @default.
• W2079641189 cites W1991765558 @default.
• W2079641189 cites W1994333658 @default.
• W2079641189 cites W1997573253 @default.
• W2079641189 cites W1998545612 @default.
• W2079641189 cites W2002760371 @default.
• W2079641189 cites W2005206163 @default.
• W2079641189 cites W2006753719 @default.
• W2079641189 cites W2009497820 @default.
• W2079641189 cites W2010216579 @default.
• W2079641189 cites W2011186673 @default.
• W2079641189 cites W2012128574 @default.
• W2079641189 cites W2020680405 @default.
• W2079641189 cites W2021209136 @default.
• W2079641189 cites W2022694214 @default.
• W2079641189 cites W2023027070 @default.
• W2079641189 cites W2024746405 @default.
• W2079641189 cites W2025851249 @default.
• W2079641189 cites W2026985086 @default.
• W2079641189 cites W2027166376 @default.
• W2079641189 cites W2030394541 @default.
• W2079641189 cites W2030692633 @default.
• W2079641189 cites W2031466513 @default.
• W2079641189 cites W2033371230 @default.
• W2079641189 cites W2034591628 @default.
• W2079641189 cites W2036269164 @default.
• W2079641189 cites W2037114652 @default.
• W2079641189 cites W2038721026 @default.
• W2079641189 cites W2040407169 @default.
• W2079641189 cites W2040791336 @default.
• W2079641189 cites W2044571535 @default.
• W2079641189 cites W2044967228 @default.
• W2079641189 cites W2045435474 @default.
• W2079641189 cites W2049805909 @default.
• W2079641189 cites W2053050719 @default.
• W2079641189 cites W2054216914 @default.
• W2079641189 cites W2054793844 @default.
• W2079641189 cites W2056650464 @default.
• W2079641189 cites W2058738049 @default.
• W2079641189 cites W2063335334 @default.
• W2079641189 cites W2064892351 @default.
• W2079641189 cites W2067303727 @default.
• W2079641189 cites W2068058707 @default.
• W2079641189 cites W2068730157 @default.
• W2079641189 cites W2072235832 @default.
• W2079641189 cites W2072557751 @default.
• W2079641189 cites W2073623673 @default.
• W2079641189 cites W2074646736 @default.
• W2079641189 cites W2078503418 @default.
• W2079641189 cites W2078771835 @default.
• W2079641189 cites W2080394812 @default.
• W2079641189 cites W2082136301 @default.
• W2079641189 cites W2083478499 @default.
• W2079641189 cites W2086163572 @default.
• W2079641189 cites W2086472885 @default.
• W2079641189 cites W2086802263 @default.
• W2079641189 cites W2087808523 @default.
• W2079641189 cites W2089198801 @default.
• W2079641189 cites W2089535673 @default.
• W2079641189 cites W2090172634 @default.
• W2079641189 cites W2090404699 @default.
• W2079641189 cites W2091864802 @default.
• W2079641189 cites W2095770779 @default.
• W2079641189 cites W2098482961 @default.
• W2079641189 cites W2099615748 @default.
• W2079641189 cites W2102515376 @default.
• W2079641189 cites W2107623126 @default.
• W2079641189 cites W2108201978 @default.
• W2079641189 cites W2117875288 @default.
• W2079641189 cites W2130916952 @default.
• W2079641189 cites W2134288587 @default.

• next