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- W2079653953 endingPage "8436" @default.
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- W2079653953 abstract "Ph3P-catalyzed [3 + 2] cycloaddition reaction of sulfamate-derived cyclic imines with allenoate has been developed, affording sulfamate-fused dihydropyrroles under very mild conditions in high yields. Using amino acid-based bifunctional phosphine as chiral catalyst, its asymmetric variant provided the corresponding products in good yields with moderate to excellent enantiomeric excesses (up to 91% yield and up to 98% ee). Subsequent transformations of the heterocyclic products gave various pharmaceutically attractive compounds." @default.
- W2079653953 created "2016-06-24" @default.
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- W2079653953 date "2013-08-14" @default.
- W2079653953 modified "2023-09-27" @default.
- W2079653953 title "Phosphine-Catalyzed [3 + 2] Cycloaddition of Sulfamate-Derived Cyclic Imines with Allenoate: Synthesis of Sulfamate-Fused Dihydropyrroles" @default.
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- W2079653953 doi "https://doi.org/10.1021/jo401107v" @default.
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