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- W2079658934 abstract "Effects of montmorillonite (MMT) content on the free volume hole and miscibility were first investigated for polyurethane/epoxy resin (PU/EP) interpenetrating polymer network (IPN) nanocomposites by positron annihilation lifetime spectroscopy (PALS), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FTIR). An exfoliated (IPN/MMT1), a coexistence of exfoliated and intercalated (IPN/MMT3), and an intercalated (IPN/MMT5) structures were confirmed by XRD. Influences of two kinds of hydrogen bonding interactions including both between carbonyl group and N-H group, and the other between urethane group and silicate layers have been discussed. PALS results reveal that the size of the free volume holes decreases after the MMT loaded due to the increase of chain packing efficiency. The large difference between IPN/MMT1 and IPN/MMT5 in the free volume distribution was observed. (© 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)" @default.
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- W2079658934 date "2007-09-01" @default.
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- W2079658934 title "Influence of MMT content on the microstructure and miscibility for PU/EP IPN nanocomposites by positron" @default.
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- W2079658934 doi "https://doi.org/10.1002/pssc.200675853" @default.
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