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- W2079659234 abstract "The preparation and properties of a new analog of pyridoxal phosphate, 3- (4-formyl-3-hydroxy-2-methyl-5-pyridyl)propionic acid and of the corresponding 4-aminomethyl compound are described. The n.m.r. spectrum of the new aldehyde is compared with those of 5-deoxypyridoxal and pyridoxal phosphate. The broad aldehyde proton peak of 5-deoxypyridoxal is sharpened by heating, suggesting an equilibrium between two geometrical isomers. Mass spectra of the new aldehyde and of 5-deoxypyridoxal are analyzed. The electronic absorption spectrum is nearly the same as that of 5-deoxypyridoxal. The new aldehyde undergoes rapid transamination with amino acids, and the corresponding aminomethyl compound can be reoxidized to the aldehyde by heating with glyoxylic acid in aqueous solution." @default.
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- W2079659234 date "1967-09-01" @default.
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- W2079659234 title "Synthesis of vitamin B<sub>6</sub>derivatives. III. 3- (4-formyl-3-hydroxy-2-methyl-5-pyridyl)propionic acid, an analog of pyridoxal phosphate" @default.
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- W2079659234 doi "https://doi.org/10.1002/jhet.5570040302" @default.
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