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- W2079662625 abstract "Abstract Thermodynamic data have been obtained by calorimetric titration in toluene at 30°C for the formation of adducts of Ph 2 Cd and Ph 2 Zn with heterocyclic bases. Cd readily becomes 4-coordinate, forming very stable 1/1 adducts with o -phen, bipy or tmed and both 1/1 and2/1 adducts with 4-methylpyridine. Zn prefers to become 3-coordinate, forming very stable adducts (Ph 2 Zn) 2 B with phen, bipy or tmed; only phen forms a 1/1 adduct and its enthalpy of formation is little greater. With 4-methylpyridine a stable1/1 adduct is formed, but addition of further base is incomplete even with a large excess of base." @default.
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- W2079662625 date "1979-05-01" @default.
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- W2079662625 title "Thermodynamics of metalligand bond formation" @default.
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- W2079662625 doi "https://doi.org/10.1016/s0022-328x(00)88058-4" @default.
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